LiFePO4 – What is It? And How Does It Differ From Lithium-Ion Batteries?
If you’ve read the Lithium ion battery guide, you may have come across LiFePO4 (lithium-iron-phosphate) and its many uses. But what is LiFePO4? And how does it differ from lithium-ion batteries? We’ll talk about these topics in this article. But before we get started, let’s briefly look at LiFePO4’s pros and cons.
Lithium ion
Although both types of batteries have similar properties, lithium ion batteries are more powerful than LiFePO4 ones. Their specific energy is also higher and their discharge rate is faster. Besides, they can both carry a full charge and discharge it in about one-quarter of a cycle. So, it’s important to know which type is best for your needs. Continue reading to learn about the differences between these two types of batteries.
There are many advantages to using lithium batteries. The energy density is significantly higher, and they have a longer life span than other battery chemistries. Lithium iron phosphate batteries are safer to use and are often housed in residences or office buildings. Both types of batteries are capable of high discharge rates and can withstand high temperatures. If you need a battery with a high discharge rate, however, lithium ion is better.
Both LiFePO4 and lithium ion batteries are powerful and lightweight. However, both batteries can be expensive. The biggest benefit of the former is their high discharge rates and low self-discharge rate. LiFePO4 is better suited for smaller devices that don’t need a high capacity. However, fast charging can cause thermal instability and short-circuiting, so it is important to store your battery safely in dry locations.
The main differences between lithium ion and LiFePO4 batteries lie in their chemical makeup. Lithium iron phosphate, or LiFePO4, is a lithium chemistry that is incredibly stable. It is a naturally safe cathode material, and its iron phosphate provides an extremely strong molecular bond that keeps the battery safe even under extreme conditions. It is also incombustible, making it a safer option for battery applications.
There are also significant differences between lithium ion and LiFePO4 batteries. LiFePO4 batteries can last between 3,000 and 5,000 cycles. This means that they have higher average costs but can be used for longer periods of time. The only downside to LiFePO4 is that they can’t be used as much as lithium ion batteries. However, they can be used for many years, and they don’t have over-discharge problems.
One difference between lithium ion and LiFePO4 batteries is the voltage range they support. Lithium ion batteries have a very narrow Voltage range, and exceeding this can permanently damage the battery. Similarly, LiFePO4 batteries have a wide range of operating voltage from 8.0V to 16.8V. LiFePO4 batteries are better suited for low-voltage applications, such as GPS systems.
Besides the differences in the storage capacity between lithium ion and LiFePO4 batteries, their safety is another big advantage. LiFePO4 batteries are less likely to explode or catch fire in dangerous circumstances, which reduces the risk of injury or death. Therefore, they are best suited for applications where safety is of utmost importance. However, there are also advantages and disadvantages to each type of battery.
The charging process for both LiFePO4 and lithium ion batteries is similar. A solar cell charge controller regulates the voltage and current of the cells and feeds it to the battery management system. Moreover, a solar cell charge controller also provides additional protections, such as over-voltage, under-voltage, and short circuit. These controllers also provide load balancing.
Lithium polymer
The LiFePO4 battery is a good solution for a high-discharge-rate, high-temperature battery. The lithium iron phosphate cathode allows it to be used in high-capacity lithium batteries without fear of explosion or puncture. Its high cycle life and fast charging make it a good choice for many applications. LiFePO4 batteries are also environmentally friendly and relatively inexpensive, making them an excellent choice for portable power applications.
In the RC industry, LiFePO4 batteries are the most popular type of rechargeable battery. Lithium ions move from the positive electrode to the negative electrode through a polymer membrane. A carbon atoms-based negative electrode separates the lithium ions from the positive electrode. The battery’s positive electrode is a graphite carbon electrode. LiFePO4 acts as the cathode.
In addition to their superior performance, LiFePO4 batteries are lightweight and space-efficient. They are about one third the weight of lead acid batteries and only half that of manganese oxide. And while lithium batteries do not produce toxic emissions, they are still environmentally friendly, as they do not contain rare earth metals. It is also a safer choice for use in hazardous environments because they do not leak and do not overheat.
Despite being more expensive and less durable than their lead-acid counterparts, lithium-polymer batteries are still superior to their lead-acid cousins. Compared to lead-acid batteries, lithium-polymer batteries are also lightweight. They are also more effective in constant-mode operation. Arora et al. showed that phase diffusion was the major limiting factor for high discharge currents in plastic lithium-ion batteries.
Compared to Cobalt and nickel, LiFePO4 lithium batteries can handle high temperatures without undergoing overheating. Lithium-polymer batteries are more stable. In addition, LiFePO4 lithium polymer batteries are highly resistant to thermal runaway. The polymer separators are multilayer structures made of a layered structure of polyethylene and polypropylene. These layers provide support to the lithium and ion transport and complete the electrical circuit.
While LiFePO4 is less energy-dense than Lithium-Ion, it does not need a full charge to be useful. LiFePO4 batteries can be connected in parallel without damage to each other. Because the cells don’t self-discharge, they can be left in the open for several months without losing any juice. And with its long life cycle, the LiFePO4 battery has a higher capacity and a longer lifespan than lithium-Ion.
The advantage of LiFePO4 over Li-ion is that it can be manufactured with lower voltages. In fact, higher voltages can be produced by using a BMS, which allows batteries to reach a higher voltage before being disconnected. Although the higher voltages are possible, the downside is that they have no benefits and can cause damage. If you are considering LiFePO4 as a solution for your next portable power solution, you should do your homework.
Another advantage of LiFePO4 batteries is their low-temperature capability. As the electrolyte doesn’t contain water, the battery will not expand or contract during freezing, making them an excellent choice for portable energy storage. But you must also take into consideration the temperature and charging cycle. LiFePO4 batteries are best charged at -20 degrees Celsius. Otherwise, their capacity will decrease. In addition, they suffer from slightly faster aging compared to their lead-acid batteries.